This term can, IMHO, best be understood as an antonym of faithful, which is a common English word.
Definition of faithful (Entry 1 of 2)
1: steadfast in affection or allegiance : LOYAL
a faithful friend
2: firm in adherence to promises or in observance of duty : CONSCIENTIOUS
a faithful employee
The 2nd meaning (there are others) is the one of interest here.
Somehow who takes on a duty to vote as per the choices of the electorate, who then breaks from that duty is not being faithful.
(However take into account that they could still be deemed to be performing their role as intended by the founders of the US government, who often wanted to uncouple sober governance from the hot-headed impulses of the people which was one of the motivations for the electoral college system.)
While unfaithful , a more common word, seems like it could be used instead, that word is more reserved for use in a marital/sexual context.