Yes - I commented a few weeks ago that Le Monde had reported that, according to an unnamed diplomatic source, France had delivered 'a few dozen' MILAN anti-tank guided missiles to Ukraine - my translation below:
Between 25 and 28 February, Paris, like other European capitals, provided protective equipment, helmets and bulletproof vests. But since then, according to our information, France has been delivering Milan anti-tank missiles to Ukrainian fighters. Taken from French army stocks, the quantity appears, for the time being, to have remained modest - "a few dozen", between 28 February and 3 March, according to a diplomatic source.
More recently, footage has emerged of Ukrainian troops being trained on the use of these missiles. A report by CNN on the Mozart Group, headed by retired US Marine Andy Milburn, which is providing support to the Ukrainian forces, contained a few brief clips of these systems on the ground in Ukraine - at 1:30 and 2:36 - screenshot from the first clip below with the 'MILAN' logo visible on the weapon case. As far as I'm aware, this report on April 12th is the first footage of French weapons on the ground in Ukraine.